Comptes rendus academie des sciences, chimie, t.10, fascicule 8, aout 2007 : metaux en biocatalyse : d

• Date de parution : 07/09/2007
• Editeur : Elsevier
• EAN : 9782756202303
• Série : (-)
• Support : Revue

• Nombre de pages : (-)
• Collection : (-)
• Genre : Sciences appliquées
• Thème : Sciences appliquées
• Prix littéraire(s) : (-)

Avant-propos/Foreword. Second generation artificial hydrogenases based on the biotin-avidin technology: improving selectivity and organic solvent tolerance by introduction of an (R)-proline spacer. New biocatalysts mimicking oxidative hemoproteins: Hemoabzymes. Diiron-containing metalloproteins:... Voir plus

Avant-propos/Foreword. Second generation artificial hydrogenases based on the biotin-avidin technology: improving selectivity and organic solvent tolerance by introduction of an (R)-proline spacer. New biocatalysts mimicking oxidative hemoproteins: Hemoabzymes. Diiron-containing metalloproteins: developing functional models. Iridium aminyl radical complexes as catalysts for the catalytic dehydrogenation of primary hydroxyl functions in natural products. Xanthine oxidase-assisted catalysis by dopamine -hydroxylase: mechanistic considerations on the role of superoxide anion. ATP- and redox-induced conformational changes in the activator of the radical enzyme 2-hydroxyisocaproyl-CoA dehydratase. Isoprenoid biosynthesis via the methylerythritol phosphate pathway: GcpE and LytB, two novel iron-sulphur proteins. Characterization of the DNA repair spore photoproduct lyase enzyme from Clostridium acetobutylicum: a radical-SAM enzyme. Hybrid density functional study of the oxidized states of NiFe-hydrogenase.